Вестник БГУ. Химия. Физика
Библиографическое описание:
, , , Сравнительная оценка оптической нелинейности представителей семейства шортитоподобных двойных боратов Na3RE2(BO3)3 (RE = La, Pr, Nd, Sm, Eu) // Вестник БГУ. Химия. Физика. - 2024. №4. . - С. 15-23.
Заглавие:
Сравнительная оценка оптической нелинейности представителей семейства шортитоподобных двойных боратов Na3RE2(BO3)3 (RE = La, Pr, Nd, Sm, Eu)
Финансирование:
Работа выполнена в рамках государственного задания БИП СО РАН (проект № 0273- 2021-0008). Исследования методами порошковой рентгеновской дифракции проводились с использованием ресурсов Центра коллективного пользования научным оборудованием БИП СО РАН.
Коды:
Аннотация:
По керамической технологии получены двойные бораты состава Na3RE2(BO3)3 (RE = La, Pr, Nd, Sm, Eu). Na3Pr2(BO3)3 и Na3Eu2(BO3)3 синтезированы впервые. Соединения кристаллизуются в структурном типе шортита с пр. гр. Amm2, параметры их элементарных ячеек уточнены методом Ле-Бейля. С использованием порошковой методики Курца — Перри проведена оценка оптической нелинейности этих фаз. Значения интенсивности генерации второй гармоники в порошках исследованных боратов по отношению к α-SiO2 находятся в диапазоне от 7 до 10 и увеличиваются с ростом ионного радиуса лантаноида.
Ключевые слова:
двойные бораты, РЗЭ, синтез, ГВГ, нелинейно-оптические свойства.
Список литературы:
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Mutailipu M., Poeppelmeier K., and Pan S., Borates: a rich source for optical materials. Chemical Reviews. 2021; 121(3): 1130–1202. URL: https://doi.org/10.1021/ acs.chemrev.0c00796
Zhang G., Li Y., Fu P. at all. Crystal structure of sodium lanthanum borate Na3La2(BO3)3. Journal of synthetic crystals. 2004; 33 (4): 490–495. URL: http://rgjtxb. jtxb.cn/EN/Y2004/V33/I4/490
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Mascetti J., Fouassier C., Hagenmuller P. Concentration quenching of the Nd3+ emission in alkali rare earth borates. Journal of Solid State Chemistry. 1983; 50 (2): 204-212. URL: https://doi.org/10.1016/0022-4596(83)90189-5
Kuznetsov A. B., Jamous A. Y., Svetlichnyi V. A., K. A. Kokh. Phase relations between Na3Nd(BO3)2, Na3Nd2(BO3)3, NdBO3 and their luminescence properties. J Struct Chem. 2024; 65: 1736–1747. URL: https://doi.org/10.1134/S0022476624090051
Zhang G., Wu Y., Fu P. at all. A new nonlinear optical borate crystal Na3La2(BO3)3. Chemistry Letters. 2001; 30(5): 456–457. URL: https://doi.org/10.1246/ cl.2001.456
Kurtz S. K., Perry T. T. A powder technique for the evaluation of nonlinear optical mate- rials. J. Appl. Phys. 1986; 39: 3798–3813. URL: https://doi.org/10.1063/1.1656857
Coelho A. A. TOPAS and TOPAS-Academic: an optimization program integrating com- puter algebra and crystallographic objects written in C++. Journal of Applied Crystallography. 2018; 51: 210–218. URL: https://doi.org/10.1107/S1600576718000183
Dekker P., Dawes J. M., Piper J. A. at all. 1.1 W CW self-frequency-doubled diode- pumped Yb:YAl3(BO3)4 laser. Opt Commun. 2001; 195(5–6): 431–436. URL: https://doi.org/10.1016/S0030-4018(01)01347-5
Ilas S., Loiseau P., Aka G., Taira T. 240 kW peak power at 266 nm in nonlinear YAl3(BO3)4 single crystal. Optics Express. 2014; 22(24); 30325–30332. URL: https://doi.org/10.1364/OE.22.030325
Le Bail A., Jouanneaux A. A Qualitative account for anisotropic broadening in wholepowder-diffraction-pattern fitting by second-rank tensors. J. Appl. Cryst. 1997; 30: 265–271. URL: https://doi.org/10.1107/S0021889896011922
Järvinen M. Application of symmetrized harmonics expansion to correction of the pre- ferred orientation effect. Journal of Applied Crystallography. 1993; 26(4): 525–531. URL: https://doi.org/10.1107/S0021889893001219
Shannon R. D. Revised effective ionic radii and systematic studies of interatomic dis- tances in halides and chalcogenides. Acta Crystallographica. 1976; 32: 751–767. URL: https://doi.org/10.1107/S0567739476001551.
Miriding M., Zhang M., Yang Z., and Pan S. Targeting the next generation of deep- ultraviolet nonlinear. Optical materials: expanding from borates to borate fluorides to fluoroox- oborates. Acc. Chem. Res. 2019; 52(3): 791–801. URL: https://doi.org/10.1021/ acs.accounts.8b00649.
Xie Z., Mutailipu M., He G. at all. A series of rare-earth borates K7MRE2B15O30 (M = Zn, Cd, Pb; RE = Sc, Y, Gd, Lu) with large second harmonic generation responses. Chemistry of materials. 2018; 30(7): 2414-2423. URL: https://doi.org/10.1021/acs.chemmater.8b00491.
Kuz’min N. N., Boldyrev K. N., Leonyuk N. I. at all. Luminescence and nonlinear optical properties of borates LnGa3(BO3)4 (Ln = Nd, Sm, Tb, Er, Dy, or Ho). Opt. Spectrosc. 2019; 127: 107–112. URL: https://doi.org/10.1134/S0030400X19070154.
Beskorovaynaya D. A., Deyneko D. V., Baryshnikova O. V. at all. Optical non-linearity tuning in Ca8-xPbxMBi(VO4)7 whitlockite-type systems. Journal of Alloys and Compounds. 2016; 672: 1–8. URL: https://doi.org/10.1016/j.jallcom.2016.02.218.
Mutailipu M., Poeppelmeier K., and Pan S., Borates: a rich source for optical materials. Chemical Reviews. 2021; 121(3): 1130–1202. URL: https://doi.org/10.1021/ acs.chemrev.0c00796
Zhang G., Li Y., Fu P. at all. Crystal structure of sodium lanthanum borate Na3La2(BO3)3. Journal of synthetic crystals. 2004; 33 (4): 490–495. URL: http://rgjtxb. jtxb.cn/EN/Y2004/V33/I4/490
Zhao S., Zhang G., Zhang X. at all. Growth and optical properties of Na3Gd2(BO3)3 crys- tal. Opt Mater. 2012; 34(8): 1464–1467. URL: https://doi.org/10.1016/ j.optmat.2012.03.002.
Zhang G., Wu Y., Fu P. at all. A new sodium samarium borate Na3Sm2(BO3)3. J Phys Chem Solids. 2002; 63(1): 145–146. URL: https://doi.org/10.1016/ S0022-3697(01)00090-7
Mascetti J., Fouassier C., Hagenmuller P. Concentration quenching of the Nd3+ emission in alkali rare earth borates. Journal of Solid State Chemistry. 1983; 50 (2): 204-212. URL: https://doi.org/10.1016/0022-4596(83)90189-5
Kuznetsov A. B., Jamous A. Y., Svetlichnyi V. A., K. A. Kokh. Phase relations between Na3Nd(BO3)2, Na3Nd2(BO3)3, NdBO3 and their luminescence properties. J Struct Chem. 2024; 65: 1736–1747. URL: https://doi.org/10.1134/S0022476624090051
Zhang G., Wu Y., Fu P. at all. A new nonlinear optical borate crystal Na3La2(BO3)3. Chemistry Letters. 2001; 30(5): 456–457. URL: https://doi.org/10.1246/ cl.2001.456
Kurtz S. K., Perry T. T. A powder technique for the evaluation of nonlinear optical mate- rials. J. Appl. Phys. 1986; 39: 3798–3813. URL: https://doi.org/10.1063/1.1656857
Coelho A. A. TOPAS and TOPAS-Academic: an optimization program integrating com- puter algebra and crystallographic objects written in C++. Journal of Applied Crystallography. 2018; 51: 210–218. URL: https://doi.org/10.1107/S1600576718000183
Dekker P., Dawes J. M., Piper J. A. at all. 1.1 W CW self-frequency-doubled diode- pumped Yb:YAl3(BO3)4 laser. Opt Commun. 2001; 195(5–6): 431–436. URL: https://doi.org/10.1016/S0030-4018(01)01347-5
Ilas S., Loiseau P., Aka G., Taira T. 240 kW peak power at 266 nm in nonlinear YAl3(BO3)4 single crystal. Optics Express. 2014; 22(24); 30325–30332. URL: https://doi.org/10.1364/OE.22.030325
Le Bail A., Jouanneaux A. A Qualitative account for anisotropic broadening in wholepowder-diffraction-pattern fitting by second-rank tensors. J. Appl. Cryst. 1997; 30: 265–271. URL: https://doi.org/10.1107/S0021889896011922
Järvinen M. Application of symmetrized harmonics expansion to correction of the pre- ferred orientation effect. Journal of Applied Crystallography. 1993; 26(4): 525–531. URL: https://doi.org/10.1107/S0021889893001219
Shannon R. D. Revised effective ionic radii and systematic studies of interatomic dis- tances in halides and chalcogenides. Acta Crystallographica. 1976; 32: 751–767. URL: https://doi.org/10.1107/S0567739476001551.
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